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Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M

Transition metal (Cu, Ni, Co) doped MnAl mixed oxide catalysts were prepared through a novel method involving the calcination of hydrotalcite precursors for the selective catalytic reduction of NO(x) with NH(3) (NH(3)-SCR). The effects of transition metal modification were confirmed by means of XRD,...

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Detalles Bibliográficos
Autores principales: Du, Yali, Liu, Lili, Feng, Yalin, Yang, Baoshuan, Wu, Xu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076116/
https://www.ncbi.nlm.nih.gov/pubmed/35541372
http://dx.doi.org/10.1039/c9ra08391j
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author Du, Yali
Liu, Lili
Feng, Yalin
Yang, Baoshuan
Wu, Xu
author_facet Du, Yali
Liu, Lili
Feng, Yalin
Yang, Baoshuan
Wu, Xu
author_sort Du, Yali
collection PubMed
description Transition metal (Cu, Ni, Co) doped MnAl mixed oxide catalysts were prepared through a novel method involving the calcination of hydrotalcite precursors for the selective catalytic reduction of NO(x) with NH(3) (NH(3)-SCR). The effects of transition metal modification were confirmed by means of XRD, BET, TEM, XPS, NH(3)-TPD, and H(2)-TPR measurements. Experimental results evidenced that CoMnAl-LDO presented the highest NO(x) removal efficiency of over 80% and a relatively high N(2) selectivity of over 88% in a broad working temperature range (150–300 °C) among all the samples studied. Moreover, the CoMnAl-LDO sample possessed better stability and excellent resistance to H(2)O and SO(2). The reasons for such results could be associated with the good dispersion of Co(3)O(4) and MnO(x), which could consequently provide optimum redox behavior, plentiful acid sites, and strong NO(x) adsorption ability. Furthermore, dynamics calculations verified the meaningful reduction in apparent activation energy (E(a)) for the CoMnAl-LDO sample, which is in agreement with the DeNO(x) activity.
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spelling pubmed-90761162022-05-09 Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M Du, Yali Liu, Lili Feng, Yalin Yang, Baoshuan Wu, Xu RSC Adv Chemistry Transition metal (Cu, Ni, Co) doped MnAl mixed oxide catalysts were prepared through a novel method involving the calcination of hydrotalcite precursors for the selective catalytic reduction of NO(x) with NH(3) (NH(3)-SCR). The effects of transition metal modification were confirmed by means of XRD, BET, TEM, XPS, NH(3)-TPD, and H(2)-TPR measurements. Experimental results evidenced that CoMnAl-LDO presented the highest NO(x) removal efficiency of over 80% and a relatively high N(2) selectivity of over 88% in a broad working temperature range (150–300 °C) among all the samples studied. Moreover, the CoMnAl-LDO sample possessed better stability and excellent resistance to H(2)O and SO(2). The reasons for such results could be associated with the good dispersion of Co(3)O(4) and MnO(x), which could consequently provide optimum redox behavior, plentiful acid sites, and strong NO(x) adsorption ability. Furthermore, dynamics calculations verified the meaningful reduction in apparent activation energy (E(a)) for the CoMnAl-LDO sample, which is in agreement with the DeNO(x) activity. The Royal Society of Chemistry 2019-12-02 /pmc/articles/PMC9076116/ /pubmed/35541372 http://dx.doi.org/10.1039/c9ra08391j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Du, Yali
Liu, Lili
Feng, Yalin
Yang, Baoshuan
Wu, Xu
Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M
title Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M
title_full Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M
title_fullStr Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M
title_full_unstemmed Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M
title_short Enhancement of NH(3)-SCR performance of LDH-based MMnAl (M = Cu, Ni, Co) oxide catalyst: influence of dopant M
title_sort enhancement of nh(3)-scr performance of ldh-based mmnal (m = cu, ni, co) oxide catalyst: influence of dopant m
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076116/
https://www.ncbi.nlm.nih.gov/pubmed/35541372
http://dx.doi.org/10.1039/c9ra08391j
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