Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions

A crystalline 14-metal Zn–Nd cluster [Zn(6)Nd(8)L(2)(OAc)(20)(O)(2)(NO(3))(4)(OC(2)H(5))(4)] (1) was constructed using a flexible Schiff base ligand with long-chain (CH(2))(2)O(CH(2))(2)O(CH(2))(2) backbone. 1 exhibits a nanoscale rectangular structure (10 × 14 × 18 Å). Besides the visible ligand-ce...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Jieni, Yang, Xiaoping, Zhu, Ting, Yuan, Bichen, Chen, Hongfen, Shi, Dongliang, Schipper, Desmond, Jones, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076200/
https://www.ncbi.nlm.nih.gov/pubmed/35541392
http://dx.doi.org/10.1039/c9ra09409a
_version_ 1784701861745393664
author Liu, Jieni
Yang, Xiaoping
Zhu, Ting
Yuan, Bichen
Chen, Hongfen
Shi, Dongliang
Schipper, Desmond
Jones, Richard A.
author_facet Liu, Jieni
Yang, Xiaoping
Zhu, Ting
Yuan, Bichen
Chen, Hongfen
Shi, Dongliang
Schipper, Desmond
Jones, Richard A.
author_sort Liu, Jieni
collection PubMed
description A crystalline 14-metal Zn–Nd cluster [Zn(6)Nd(8)L(2)(OAc)(20)(O)(2)(NO(3))(4)(OC(2)H(5))(4)] (1) was constructed using a flexible Schiff base ligand with long-chain (CH(2))(2)O(CH(2))(2)O(CH(2))(2) backbone. 1 exhibits a nanoscale rectangular structure (10 × 14 × 18 Å). Besides the visible ligand-centered emission, 1 displays typical NIR luminescence of Nd(3+). Interestingly, 1 shows both a ligand-centered and lanthanide fluorescence response towards metal ions, especially to K(+) and Co(2+) at the ppm level.
format Online
Article
Text
id pubmed-9076200
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90762002022-05-09 Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions Liu, Jieni Yang, Xiaoping Zhu, Ting Yuan, Bichen Chen, Hongfen Shi, Dongliang Schipper, Desmond Jones, Richard A. RSC Adv Chemistry A crystalline 14-metal Zn–Nd cluster [Zn(6)Nd(8)L(2)(OAc)(20)(O)(2)(NO(3))(4)(OC(2)H(5))(4)] (1) was constructed using a flexible Schiff base ligand with long-chain (CH(2))(2)O(CH(2))(2)O(CH(2))(2) backbone. 1 exhibits a nanoscale rectangular structure (10 × 14 × 18 Å). Besides the visible ligand-centered emission, 1 displays typical NIR luminescence of Nd(3+). Interestingly, 1 shows both a ligand-centered and lanthanide fluorescence response towards metal ions, especially to K(+) and Co(2+) at the ppm level. The Royal Society of Chemistry 2019-12-04 /pmc/articles/PMC9076200/ /pubmed/35541392 http://dx.doi.org/10.1039/c9ra09409a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Liu, Jieni
Yang, Xiaoping
Zhu, Ting
Yuan, Bichen
Chen, Hongfen
Shi, Dongliang
Schipper, Desmond
Jones, Richard A.
Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions
title Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions
title_full Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions
title_fullStr Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions
title_full_unstemmed Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions
title_short Construction of a crystalline 14-metal Zn–Nd rectangular nanocluster with a dual-emissive response towards metal ions
title_sort construction of a crystalline 14-metal zn–nd rectangular nanocluster with a dual-emissive response towards metal ions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076200/
https://www.ncbi.nlm.nih.gov/pubmed/35541392
http://dx.doi.org/10.1039/c9ra09409a
work_keys_str_mv AT liujieni constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT yangxiaoping constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT zhuting constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT yuanbichen constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT chenhongfen constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT shidongliang constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT schipperdesmond constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions
AT jonesricharda constructionofacrystalline14metalznndrectangularnanoclusterwithadualemissiveresponsetowardsmetalions

Ejemplares similares