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Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate
The Ca–Al and Ca–Al–X (X = F(−), Cl(−) and Br(−)) catalysts were prepared via thermal decomposition of Ca–Al layered double hydroxides (LDHs), and tested for methanolysis of propylene carbonate (PC) to produce dimethyl carbonate (DMC). The catalytic performance of these catalysts increased in the or...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076883/ https://www.ncbi.nlm.nih.gov/pubmed/35538981 http://dx.doi.org/10.1039/c7ra10832j |
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author | Liao, Yunhui Li, Feng Pu, Yanfeng Wang, Feng Dai, Xin Zhao, Ning Xiao, Fukui |
author_facet | Liao, Yunhui Li, Feng Pu, Yanfeng Wang, Feng Dai, Xin Zhao, Ning Xiao, Fukui |
author_sort | Liao, Yunhui |
collection | PubMed |
description | The Ca–Al and Ca–Al–X (X = F(−), Cl(−) and Br(−)) catalysts were prepared via thermal decomposition of Ca–Al layered double hydroxides (LDHs), and tested for methanolysis of propylene carbonate (PC) to produce dimethyl carbonate (DMC). The catalytic performance of these catalysts increased in the order of Ca–Al–Br(−) < Ca–Al < Ca–Al–Cl(−) < Ca–Al–F(−), which was consistent with the strong basicity of these materials. The recyclability test results showed that the addition of Al and halogens (F(−), Cl(−) and Br(−)) not only stabilized the CaO but also improved the recyclability of the catalysts. Particularly, the Ca–Al–F(−) catalyst exerted the highest stability after 10 recycles. These catalysts have an important value for the exploitation of DMC synthesis by transesterification of PC with methanol. |
format | Online Article Text |
id | pubmed-9076883 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90768832022-05-09 Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate Liao, Yunhui Li, Feng Pu, Yanfeng Wang, Feng Dai, Xin Zhao, Ning Xiao, Fukui RSC Adv Chemistry The Ca–Al and Ca–Al–X (X = F(−), Cl(−) and Br(−)) catalysts were prepared via thermal decomposition of Ca–Al layered double hydroxides (LDHs), and tested for methanolysis of propylene carbonate (PC) to produce dimethyl carbonate (DMC). The catalytic performance of these catalysts increased in the order of Ca–Al–Br(−) < Ca–Al < Ca–Al–Cl(−) < Ca–Al–F(−), which was consistent with the strong basicity of these materials. The recyclability test results showed that the addition of Al and halogens (F(−), Cl(−) and Br(−)) not only stabilized the CaO but also improved the recyclability of the catalysts. Particularly, the Ca–Al–F(−) catalyst exerted the highest stability after 10 recycles. These catalysts have an important value for the exploitation of DMC synthesis by transesterification of PC with methanol. The Royal Society of Chemistry 2018-01-02 /pmc/articles/PMC9076883/ /pubmed/35538981 http://dx.doi.org/10.1039/c7ra10832j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Liao, Yunhui Li, Feng Pu, Yanfeng Wang, Feng Dai, Xin Zhao, Ning Xiao, Fukui Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate |
title | Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate |
title_full | Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate |
title_fullStr | Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate |
title_full_unstemmed | Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate |
title_short | Solid base catalysts derived from Ca–Al–X (X = F(−), Cl(−) and Br(−)) layered double hydroxides for methanolysis of propylene carbonate |
title_sort | solid base catalysts derived from ca–al–x (x = f(−), cl(−) and br(−)) layered double hydroxides for methanolysis of propylene carbonate |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076883/ https://www.ncbi.nlm.nih.gov/pubmed/35538981 http://dx.doi.org/10.1039/c7ra10832j |
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