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Aggregation of catalytically active Ru nanoparticles to inactive bulk, monitored in situ during an allylic isomerization reaction. Influence of solvent, surfactant and stirring
The exploration of catalytic isomerization reactions of an allylic alcohol to ketone, in the presence of μ-oxo-triruthenium acetate as a precatalyst in alcohol solvents, has established that the catalyst is heterogeneous in nature and proceeds by means of the in situ formed Ru(0) nanoparticles (Ru(0...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077127/ https://www.ncbi.nlm.nih.gov/pubmed/35540901 http://dx.doi.org/10.1039/c7ra11133a |