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Facile synthesis of high-surface-area nanoporous carbon from biomass resources and its application in supercapacitors

It is critical for nanoporous carbons to have a large surface area, and low cost and be readily available for challenging energy and environmental issues. The pursuit of all three characteristics, particularly large surface area, is a formidable challenge because traditional methods to produce porou...

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Detalles Bibliográficos
Autores principales: Yao, Yuechao, Zhang, Qi, Liu, Peng, Yu, Liang, Huang, Lin, Zeng, Shao-Zhong, Liu, Lijia, Zeng, Xierong, Zou, Jizhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077209/
https://www.ncbi.nlm.nih.gov/pubmed/35542586
http://dx.doi.org/10.1039/c7ra12525a
Descripción
Sumario:It is critical for nanoporous carbons to have a large surface area, and low cost and be readily available for challenging energy and environmental issues. The pursuit of all three characteristics, particularly large surface area, is a formidable challenge because traditional methods to produce porous carbon materials with a high surface area are complicated and expensive, frequently resulting in pollution (commonly from the activation process). Here we report a facile method to synthesize nanoporous carbon materials with a high surface area of up to 1234 m(2) g(−1) and an average pore diameter of 0.88 nm through a simple carbonization procedure with carefully selected carbon precursors (biomass material) and carbonization conditions. It is the high surface area that leads to a high capacitance (up to 213 F g(−1) at 0.1 A g(−1)) and a stable cycle performance (6.6% loss over 12 000 cycles) as shown in a three-electrode cell. Furthermore, the high capacitance (107 F g(−1) at 0.1 A g(−1)) can be obtained in a supercapacitor device. This facile approach may open a door for the preparation of high surface area porous carbons for energy storage.