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Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework

A novel POM-based trinuclear copper(ii) triazole framework, namely, [H(2){Cu(6)(trz)(6)(μ(3)-OH)(2)}Mo(5)O(18)]·3H(2)O (1) was isolated using a hydrothermal method, which displays a 3D network constructed from trinuclear copper(ii) units and triazole ligands with [Mo(5)O(18)](6−) anions as templates...

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Autores principales: Xu, Li, Lu, Ying, Huang, Liping, Li, Xiaohui, Wang, Shuang, Zhang, Zhong, Liu, Shuxia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077210/
https://www.ncbi.nlm.nih.gov/pubmed/35542599
http://dx.doi.org/10.1039/c7ra12150d
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author Xu, Li
Lu, Ying
Huang, Liping
Li, Xiaohui
Wang, Shuang
Zhang, Zhong
Liu, Shuxia
author_facet Xu, Li
Lu, Ying
Huang, Liping
Li, Xiaohui
Wang, Shuang
Zhang, Zhong
Liu, Shuxia
author_sort Xu, Li
collection PubMed
description A novel POM-based trinuclear copper(ii) triazole framework, namely, [H(2){Cu(6)(trz)(6)(μ(3)-OH)(2)}Mo(5)O(18)]·3H(2)O (1) was isolated using a hydrothermal method, which displays a 3D network constructed from trinuclear copper(ii) units and triazole ligands with [Mo(5)O(18)](6−) anions as templates. 1 has been identified by single crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and FT-IR. Magnetic studies indicate that antiferromagnetic interactions exist in 1. In addition, 1 exhibits good Lewis acid catalytic activity for the synthesis of cyclohexanone ethylene ketal with 95% conversion. The HOMO–LUMO gap (E(g)) of 1 is 2.34 eV calculated using the Kubelka–Munk equation (Fhν)(0.5), indicating that its forbidden bandwidth belongs to the semiconductor category. Visible-light photodegradation of RhB catalyzed by 1 was investigated, which shows high activity with an above 98% degradation rate.
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spelling pubmed-90772102022-05-09 Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework Xu, Li Lu, Ying Huang, Liping Li, Xiaohui Wang, Shuang Zhang, Zhong Liu, Shuxia RSC Adv Chemistry A novel POM-based trinuclear copper(ii) triazole framework, namely, [H(2){Cu(6)(trz)(6)(μ(3)-OH)(2)}Mo(5)O(18)]·3H(2)O (1) was isolated using a hydrothermal method, which displays a 3D network constructed from trinuclear copper(ii) units and triazole ligands with [Mo(5)O(18)](6−) anions as templates. 1 has been identified by single crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and FT-IR. Magnetic studies indicate that antiferromagnetic interactions exist in 1. In addition, 1 exhibits good Lewis acid catalytic activity for the synthesis of cyclohexanone ethylene ketal with 95% conversion. The HOMO–LUMO gap (E(g)) of 1 is 2.34 eV calculated using the Kubelka–Munk equation (Fhν)(0.5), indicating that its forbidden bandwidth belongs to the semiconductor category. Visible-light photodegradation of RhB catalyzed by 1 was investigated, which shows high activity with an above 98% degradation rate. The Royal Society of Chemistry 2018-01-09 /pmc/articles/PMC9077210/ /pubmed/35542599 http://dx.doi.org/10.1039/c7ra12150d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Xu, Li
Lu, Ying
Huang, Liping
Li, Xiaohui
Wang, Shuang
Zhang, Zhong
Liu, Shuxia
Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
title Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
title_full Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
title_fullStr Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
title_full_unstemmed Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
title_short Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework
title_sort synthesis and properties of a pom-based trinuclear copper(ii) triazole framework
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077210/
https://www.ncbi.nlm.nih.gov/pubmed/35542599
http://dx.doi.org/10.1039/c7ra12150d
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