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Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter

Microigniters play an important role for the reliable initiation of micro explosive devices. However, the microigniter is still limited by the low out-put energy to realize high reliability and safety. Integration of energetic materials with microigniters is an effective method to enhance the igniti...

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Autores principales: Zheng, Zilong, Zhang, Wenchao, Yu, Chunpei, Zheng, Guoqiang, Ma, Kefeng, Qin, Zhichun, Ye, Jiahai, Chao, Yimin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077334/
https://www.ncbi.nlm.nih.gov/pubmed/35541495
http://dx.doi.org/10.1039/c7ra11293a
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author Zheng, Zilong
Zhang, Wenchao
Yu, Chunpei
Zheng, Guoqiang
Ma, Kefeng
Qin, Zhichun
Ye, Jiahai
Chao, Yimin
author_facet Zheng, Zilong
Zhang, Wenchao
Yu, Chunpei
Zheng, Guoqiang
Ma, Kefeng
Qin, Zhichun
Ye, Jiahai
Chao, Yimin
author_sort Zheng, Zilong
collection PubMed
description Microigniters play an important role for the reliable initiation of micro explosive devices. However, the microigniter is still limited by the low out-put energy to realize high reliability and safety. Integration of energetic materials with microigniters is an effective method to enhance the ignition ability. In this work, a Al/Co(3)O(4) nanothermite film with a three-dimensionally ordered macroporous structure was prepared by the deposition of nanoscale Al layers using magnetron sputtering on Co(3)O(4) skeletons that are synthesized using an inverse template method. Both the uniform structure and nanoscale contact between the Al layers and the Co(3)O(4) skeletons lead to an excellent exothermicity. In order to investigate the ignition properties, a micro-energetic igniter has been fabricated by the integration of the Al/Co(3)O(4) nanothermite film with a semiconductor bridge microigniter. The thermite reactions between the nanoscale Al layer and the Co(3)O(4) skeleton extensively promote the intensity of the spark, the length in duration and the size of the area, which greatly enhance the ignition reliability of the micro-energetic igniter. Moreover, this novel design enables the micro-energetic igniter to fire the pyrotechnic Zr/Pb(3)O(4) in a gap of 3.7 mm by capacitor discharge stimulation and to keep the intrinsic instantaneity high and firing energy low. The realization of gap ignition will surely improve the safety level of initiating systems and have a significant impact on the design and application of explosive devices.
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spelling pubmed-90773342022-05-09 Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter Zheng, Zilong Zhang, Wenchao Yu, Chunpei Zheng, Guoqiang Ma, Kefeng Qin, Zhichun Ye, Jiahai Chao, Yimin RSC Adv Chemistry Microigniters play an important role for the reliable initiation of micro explosive devices. However, the microigniter is still limited by the low out-put energy to realize high reliability and safety. Integration of energetic materials with microigniters is an effective method to enhance the ignition ability. In this work, a Al/Co(3)O(4) nanothermite film with a three-dimensionally ordered macroporous structure was prepared by the deposition of nanoscale Al layers using magnetron sputtering on Co(3)O(4) skeletons that are synthesized using an inverse template method. Both the uniform structure and nanoscale contact between the Al layers and the Co(3)O(4) skeletons lead to an excellent exothermicity. In order to investigate the ignition properties, a micro-energetic igniter has been fabricated by the integration of the Al/Co(3)O(4) nanothermite film with a semiconductor bridge microigniter. The thermite reactions between the nanoscale Al layer and the Co(3)O(4) skeleton extensively promote the intensity of the spark, the length in duration and the size of the area, which greatly enhance the ignition reliability of the micro-energetic igniter. Moreover, this novel design enables the micro-energetic igniter to fire the pyrotechnic Zr/Pb(3)O(4) in a gap of 3.7 mm by capacitor discharge stimulation and to keep the intrinsic instantaneity high and firing energy low. The realization of gap ignition will surely improve the safety level of initiating systems and have a significant impact on the design and application of explosive devices. The Royal Society of Chemistry 2018-01-11 /pmc/articles/PMC9077334/ /pubmed/35541495 http://dx.doi.org/10.1039/c7ra11293a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zheng, Zilong
Zhang, Wenchao
Yu, Chunpei
Zheng, Guoqiang
Ma, Kefeng
Qin, Zhichun
Ye, Jiahai
Chao, Yimin
Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
title Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
title_full Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
title_fullStr Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
title_full_unstemmed Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
title_short Integration of the 3DOM Al/Co(3)O(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
title_sort integration of the 3dom al/co(3)o(4) nanothermite film with a semiconductor bridge to realize a high-output micro-energetic igniter
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077334/
https://www.ncbi.nlm.nih.gov/pubmed/35541495
http://dx.doi.org/10.1039/c7ra11293a
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