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Copolymerization of CO(2) and epoxides mediated by zinc organyls

Herein we report the copolymerization of CHO with CO(2) in the presence of various zinc compounds R(2)Zn (R = Et, Bu, iPr, Cy and Ph). Several zinc organyls proved to be efficient catalysts for this reaction in the absence of water and co-catalyst. Notably, readily available Bu(2)Zn reached a TON up...

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Detalles Bibliográficos
Autores principales: Wulf, Christoph, Doering, Ulrike, Werner, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077689/
https://www.ncbi.nlm.nih.gov/pubmed/35542906
http://dx.doi.org/10.1039/c7ra12535f

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