A high-activity cobalt-based MOF catalyst for [2 + 2 + 2] cycloaddition of diynes and alkynes: insights into alkyne affinity and selectivity control

This work develops a highly efficient metal–organic framework (MOF) catalyst for the straightforward synthesis of functionalized benzenes via [2 + 2 + 2] cycloaddition. As efficient cooperative catalyst for such reactions, Co-MOF-1, shows great sustainability and efficiency. This new catalytic syste...

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Detalles Bibliográficos
Autores principales: Xu, Fen, Si, Xiao-Ju, Wang, Xiao-Ning, Kou, Hao-Dong, Chen, Di-Ming, Liu, Chun-Sen, Du, Miao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077787/
https://www.ncbi.nlm.nih.gov/pubmed/35539562
http://dx.doi.org/10.1039/c7ra12136a
Descripción
Sumario:This work develops a highly efficient metal–organic framework (MOF) catalyst for the straightforward synthesis of functionalized benzenes via [2 + 2 + 2] cycloaddition. As efficient cooperative catalyst for such reactions, Co-MOF-1, shows great sustainability and efficiency. This new catalytic system can lead to the generation of a series of structurally diverse benzenes in good to excellent yields (up to 95%).

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