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Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide
A micrometer-sized hybrid crystalline material was facilely fabricated from the synergistic coordination chemistry of two types of 2-hydroxyazobenzene building blocks and cobalt ions. This hybrid crystalline material functioned as both receptor and signal reporter in cyanide (CN(−)) sensing with rat...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077790/ https://www.ncbi.nlm.nih.gov/pubmed/35539523 http://dx.doi.org/10.1039/c8ra00079d |
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author | Liu, Hai-Bo Han, He-Song Lan, Bin Xiao, Dong-Mei Liang, Jing Zhang, Zi-Ying Wang, Jing |
author_facet | Liu, Hai-Bo Han, He-Song Lan, Bin Xiao, Dong-Mei Liang, Jing Zhang, Zi-Ying Wang, Jing |
author_sort | Liu, Hai-Bo |
collection | PubMed |
description | A micrometer-sized hybrid crystalline material was facilely fabricated from the synergistic coordination chemistry of two types of 2-hydroxyazobenzene building blocks and cobalt ions. This hybrid crystalline material functioned as both receptor and signal reporter in cyanide (CN(−)) sensing with ratiometric absorption responses at 456 nm and 537 nm. The mechanism of CN(−) sensing involves partial ligand dissociation accompanied by the formation of a new organic metal–CN(−) adduct. We believe that this protocol would be valuable in achieving the expected selectivities and sensitivities for a wide variety of analytes in many chemical and biological systems in the future. |
format | Online Article Text |
id | pubmed-9077790 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90777902022-05-09 Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide Liu, Hai-Bo Han, He-Song Lan, Bin Xiao, Dong-Mei Liang, Jing Zhang, Zi-Ying Wang, Jing RSC Adv Chemistry A micrometer-sized hybrid crystalline material was facilely fabricated from the synergistic coordination chemistry of two types of 2-hydroxyazobenzene building blocks and cobalt ions. This hybrid crystalline material functioned as both receptor and signal reporter in cyanide (CN(−)) sensing with ratiometric absorption responses at 456 nm and 537 nm. The mechanism of CN(−) sensing involves partial ligand dissociation accompanied by the formation of a new organic metal–CN(−) adduct. We believe that this protocol would be valuable in achieving the expected selectivities and sensitivities for a wide variety of analytes in many chemical and biological systems in the future. The Royal Society of Chemistry 2018-01-29 /pmc/articles/PMC9077790/ /pubmed/35539523 http://dx.doi.org/10.1039/c8ra00079d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Liu, Hai-Bo Han, He-Song Lan, Bin Xiao, Dong-Mei Liang, Jing Zhang, Zi-Ying Wang, Jing Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
title | Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
title_full | Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
title_fullStr | Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
title_full_unstemmed | Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
title_short | Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
title_sort | cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077790/ https://www.ncbi.nlm.nih.gov/pubmed/35539523 http://dx.doi.org/10.1039/c8ra00079d |
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