Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts

A copper-catalyzed direct C–H arylation or vinylation of BODIPYs at the β-position by iodonium salts has been developed, which provides facile access to a variety of mono-substituted BODIPY dyes. Interestingly, β-styryl BODIPY compound 9b exhibits apparent cytotoxicity after laser irradiation, which...

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Autores principales: Ren, Wenming, Xiang, Huaijiang, Peng, Chengyuan, Musha, Zulipali, Chen, Jingjing, Li, Xin, Huang, Ruimin, Hu, Youhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078099/
https://www.ncbi.nlm.nih.gov/pubmed/35542398
http://dx.doi.org/10.1039/c7ra13070h
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author Ren, Wenming
Xiang, Huaijiang
Peng, Chengyuan
Musha, Zulipali
Chen, Jingjing
Li, Xin
Huang, Ruimin
Hu, Youhong
author_facet Ren, Wenming
Xiang, Huaijiang
Peng, Chengyuan
Musha, Zulipali
Chen, Jingjing
Li, Xin
Huang, Ruimin
Hu, Youhong
author_sort Ren, Wenming
collection PubMed
description A copper-catalyzed direct C–H arylation or vinylation of BODIPYs at the β-position by iodonium salts has been developed, which provides facile access to a variety of mono-substituted BODIPY dyes. Interestingly, β-styryl BODIPY compound 9b exhibits apparent cytotoxicity after laser irradiation, which has great potential for photodynamic therapy.
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spelling pubmed-90780992022-05-09 Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts Ren, Wenming Xiang, Huaijiang Peng, Chengyuan Musha, Zulipali Chen, Jingjing Li, Xin Huang, Ruimin Hu, Youhong RSC Adv Chemistry A copper-catalyzed direct C–H arylation or vinylation of BODIPYs at the β-position by iodonium salts has been developed, which provides facile access to a variety of mono-substituted BODIPY dyes. Interestingly, β-styryl BODIPY compound 9b exhibits apparent cytotoxicity after laser irradiation, which has great potential for photodynamic therapy. The Royal Society of Chemistry 2018-02-01 /pmc/articles/PMC9078099/ /pubmed/35542398 http://dx.doi.org/10.1039/c7ra13070h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Ren, Wenming
Xiang, Huaijiang
Peng, Chengyuan
Musha, Zulipali
Chen, Jingjing
Li, Xin
Huang, Ruimin
Hu, Youhong
Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts
title Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts
title_full Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts
title_fullStr Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts
title_full_unstemmed Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts
title_short Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts
title_sort direct c–h functionalization of difluoroboron dipyrromethenes (bodipys) at β-position by iodonium salts
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078099/
https://www.ncbi.nlm.nih.gov/pubmed/35542398
http://dx.doi.org/10.1039/c7ra13070h
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