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Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)

A detailed study of the structural, magnetic, magnetocaloric and electrical effect properties in polycrystalline manganite La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3) is presented. The X-ray diffraction pattern is consistent with a rhombohedral structure with R3̄c space group. Experimental results r...

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Detalles Bibliográficos
Autores principales: Dhahri, M., Dhahri, J., Hlil, E. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078105/
https://www.ncbi.nlm.nih.gov/pubmed/35542443
http://dx.doi.org/10.1039/c7ra12905j
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author Dhahri, M.
Dhahri, J.
Hlil, E. K.
author_facet Dhahri, M.
Dhahri, J.
Hlil, E. K.
author_sort Dhahri, M.
collection PubMed
description A detailed study of the structural, magnetic, magnetocaloric and electrical effect properties in polycrystalline manganite La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3) is presented. The X-ray diffraction pattern is consistent with a rhombohedral structure with R3̄c space group. Experimental results revealed that our compound prepared via a sol–gel method exhibits a continuous (second-order) ferromagnetic (FM) to paramagnetic (PM) phase transition around the Curie temperature (T(C) = 300 K). In addition, the magnetic entropy change was found to reach 5.25 J kg(−1) K(−1) under an applied magnetic field of 5 T, corresponding to a relative cooling power (RCP) of 236 J kg(−1). We have fitted the experimental data of resistivity using a typical numerical method (Gauss function). The simulation values such as maximum resistivity (ρ(max)) and metal–semiconductor transition temperature (T(M–Sc)), calculated from this function, showed a perfect agreement with the experimental data. The shifts of these parameters as a function of magnetic field for our sample have been interpreted. The obtained values of β and γ, determined by analyzing the Arrott plots, are found to be T(C) = 298.66 ± 0.64 K, β = 0.325 ± 0.001 and γ = 1.25 ± 0.01. The critical isotherm M (T(C), μ(0)H) gives δ = 4.81 ± 0.01. These critical exponent values are found to be consistent and comparable to those predicted by the three-dimensional Ising model with short-range interaction. Thus, the Widom scaling law [Image: see text] is fulfilled.
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spelling pubmed-90781052022-05-09 Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3) Dhahri, M. Dhahri, J. Hlil, E. K. RSC Adv Chemistry A detailed study of the structural, magnetic, magnetocaloric and electrical effect properties in polycrystalline manganite La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3) is presented. The X-ray diffraction pattern is consistent with a rhombohedral structure with R3̄c space group. Experimental results revealed that our compound prepared via a sol–gel method exhibits a continuous (second-order) ferromagnetic (FM) to paramagnetic (PM) phase transition around the Curie temperature (T(C) = 300 K). In addition, the magnetic entropy change was found to reach 5.25 J kg(−1) K(−1) under an applied magnetic field of 5 T, corresponding to a relative cooling power (RCP) of 236 J kg(−1). We have fitted the experimental data of resistivity using a typical numerical method (Gauss function). The simulation values such as maximum resistivity (ρ(max)) and metal–semiconductor transition temperature (T(M–Sc)), calculated from this function, showed a perfect agreement with the experimental data. The shifts of these parameters as a function of magnetic field for our sample have been interpreted. The obtained values of β and γ, determined by analyzing the Arrott plots, are found to be T(C) = 298.66 ± 0.64 K, β = 0.325 ± 0.001 and γ = 1.25 ± 0.01. The critical isotherm M (T(C), μ(0)H) gives δ = 4.81 ± 0.01. These critical exponent values are found to be consistent and comparable to those predicted by the three-dimensional Ising model with short-range interaction. Thus, the Widom scaling law [Image: see text] is fulfilled. The Royal Society of Chemistry 2018-01-31 /pmc/articles/PMC9078105/ /pubmed/35542443 http://dx.doi.org/10.1039/c7ra12905j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Dhahri, M.
Dhahri, J.
Hlil, E. K.
Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)
title Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)
title_full Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)
title_fullStr Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)
title_full_unstemmed Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)
title_short Large magnetic entropy change and prediction of magnetoresistance using a magnetic field in La(0.5)Sm(0.1)Sr(0.4)Mn(0.975)In(0.025)O(3)
title_sort large magnetic entropy change and prediction of magnetoresistance using a magnetic field in la(0.5)sm(0.1)sr(0.4)mn(0.975)in(0.025)o(3)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078105/
https://www.ncbi.nlm.nih.gov/pubmed/35542443
http://dx.doi.org/10.1039/c7ra12905j
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