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Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review
Biomass-derived oils are recognised as the most promising renewable resources for the production of ester-based biolubricants due to their biodegradable, non-toxic and metal adhering properties. Homogeneous acid catalysts have been conventionally used in catalytic esterification and transesterificat...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078193/ https://www.ncbi.nlm.nih.gov/pubmed/35542409 http://dx.doi.org/10.1039/c7ra11824d |
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author | Hossain, Md. Anwar Mohamed Iqbal, Mohammad Anwar Julkapli, Nurhidayatullaili Muhd San Kong, Pei Ching, Juan Joon Lee, Hwei Voon |
author_facet | Hossain, Md. Anwar Mohamed Iqbal, Mohammad Anwar Julkapli, Nurhidayatullaili Muhd San Kong, Pei Ching, Juan Joon Lee, Hwei Voon |
author_sort | Hossain, Md. Anwar |
collection | PubMed |
description | Biomass-derived oils are recognised as the most promising renewable resources for the production of ester-based biolubricants due to their biodegradable, non-toxic and metal adhering properties. Homogeneous acid catalysts have been conventionally used in catalytic esterification and transesterification for the synthesis of ester-based biolubricants. Although homogeneous acid catalysts encounter difficulty during phase separation, they exhibit superior selectivity and good stereochemistry and regiochemistry control in the reaction. Consequently, transition metal complex catalysts (also known as homogeneous organometallic catalysts) are proposed for biolubricant synthesis in order to achieve a higher selectivity and conversion. Herein, the potential of both homogeneous transition metal complexes and heterogeneous supported metal complexes towards the synthesis of biolubricants, particularly, in esterification and transesterification, as well as the upgrading process, including hydrogenation and in situ hydrogenation–esterification, is critically reviewed. |
format | Online Article Text |
id | pubmed-9078193 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90781932022-05-09 Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review Hossain, Md. Anwar Mohamed Iqbal, Mohammad Anwar Julkapli, Nurhidayatullaili Muhd San Kong, Pei Ching, Juan Joon Lee, Hwei Voon RSC Adv Chemistry Biomass-derived oils are recognised as the most promising renewable resources for the production of ester-based biolubricants due to their biodegradable, non-toxic and metal adhering properties. Homogeneous acid catalysts have been conventionally used in catalytic esterification and transesterification for the synthesis of ester-based biolubricants. Although homogeneous acid catalysts encounter difficulty during phase separation, they exhibit superior selectivity and good stereochemistry and regiochemistry control in the reaction. Consequently, transition metal complex catalysts (also known as homogeneous organometallic catalysts) are proposed for biolubricant synthesis in order to achieve a higher selectivity and conversion. Herein, the potential of both homogeneous transition metal complexes and heterogeneous supported metal complexes towards the synthesis of biolubricants, particularly, in esterification and transesterification, as well as the upgrading process, including hydrogenation and in situ hydrogenation–esterification, is critically reviewed. The Royal Society of Chemistry 2018-02-01 /pmc/articles/PMC9078193/ /pubmed/35542409 http://dx.doi.org/10.1039/c7ra11824d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Hossain, Md. Anwar Mohamed Iqbal, Mohammad Anwar Julkapli, Nurhidayatullaili Muhd San Kong, Pei Ching, Juan Joon Lee, Hwei Voon Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
title | Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
title_full | Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
title_fullStr | Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
title_full_unstemmed | Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
title_short | Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
title_sort | development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078193/ https://www.ncbi.nlm.nih.gov/pubmed/35542409 http://dx.doi.org/10.1039/c7ra11824d |
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