Synthesis and application of pillared clay heterogeneous catalysts for wastewater treatment: a review

The use of pillared interlayered clays (PILCs) as heterogenous catalysts in wastewater treatment technologies, particularly advanced oxidation processes (AOPs), is gaining popularity for the treatment of refractory wastewater effluents. The recent literature involving these solid materials is reviewed, with more focus on studies that aim at reducing the synthesis costs and escalating the synthesis process to industrial scale. Their role as active solid materials in the AOPs such as photocatalysis, catalytic wet peroxide oxidation (CWPO), the Fenton process and catalytic wet air oxidation (CWAO) of refractory organic compounds in polluted aqueous streams is also reviewed. These processes are evaluated to evidence their main direction for future research, particularly with reference to possible industrial use of these technologies to treat refractory organic wastewater using pillared clay-based catalysts. The pillared clay catalysts demonstrate good application prospects for the removal of refractory wastewater effluents using AOP technology. The reviewed studies suggest that the photocatalytic process is useful in low concentrations of these compounds, while CWPO, the Fenton process and CWAO are recommended for higher concentrations. However, catalyst development to reduce the severity of oxidation reaction conditions, with focus on the low cost, catalyst stability, reusability and environmental friendliness are the key aspects to be addressed by future research work.