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A family of 3d metal clusters based on N–N single bonds bridged quasi-linear trinuclear cores: the Mn analogue displaying single-molecule magnet behavior
The reactions of the diacylhydrazine ligands N,N′-bisalicyl-2,6-pyridine dicarbohydrazide (H(6)sphz) and N,N′-bis(3-methoxysalicyl)-2,6-pyridine dicarbohydrazide (H(6)msphz) with various 3d metal salts, afforded a series of coordination clusters, namely, [Mn(III)(2)Mn(II)(sphz)(acac)(2)(CH(3)OH)(4)]...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078267/ https://www.ncbi.nlm.nih.gov/pubmed/35540381 http://dx.doi.org/10.1039/c7ra12844d |