Aromatic alkyne insertion into six-membered cyclometalated pyridine complexes of iridium: different insertion modes and structurally novel products

Reactions of 2-benzoylpyridine or 2-benzylpyridine with [Cp*MCl(2)](2) (M = Ir, Rh) have been carried out in the presence of NaOAc in refluxing methanol, which form the corresponding six-membered cyclometalated products (1–3) except for the reaction of 2-benzylpyridine with [Cp*RhCl(2)](2). Insertio...

Descripción completa

Detalles Bibliográficos
Autores principales: Chu, Xiaodan, Zhang, Shaowei, Wang, Zhuo, Li, Tongyu, Zhu, Bolin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078379/
https://www.ncbi.nlm.nih.gov/pubmed/35540324
http://dx.doi.org/10.1039/c7ra13547e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078379/
https://www.ncbi.nlm.nih.gov/pubmed/35540324
http://dx.doi.org/10.1039/c7ra13547e

Ejemplares similares