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Aromatic alkyne insertion into six-membered cyclometalated pyridine complexes of iridium: different insertion modes and structurally novel products
Reactions of 2-benzoylpyridine or 2-benzylpyridine with [Cp*MCl(2)](2) (M = Ir, Rh) have been carried out in the presence of NaOAc in refluxing methanol, which form the corresponding six-membered cyclometalated products (1–3) except for the reaction of 2-benzylpyridine with [Cp*RhCl(2)](2). Insertio...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078379/ https://www.ncbi.nlm.nih.gov/pubmed/35540324 http://dx.doi.org/10.1039/c7ra13547e |