A new approach to improve the electrochemical performance of ZnMn(2)O(4) through a charge compensation mechanism using the substitution of Al(3+) for Zn(2+)

ZnMn(2)O(4) and Zn(1−x)Al(x)Mn(2)O(4) were synthesized by a spray drying process followed by an annealing treatment. Their structural and electrochemical characteristics were investigated by SEM, XRD, XPS, charge–discharge tests and EIS. XPS data indicate that the substitution of Al(3+) for Zn(2+) causes manganese to be in a mixed valence state by a charge compensation mechanism. Moreover, the presence of this charge compensation significantly improves the electrochemical performance of Zn(1−x)Al(x)Mn(2)O(4), such as increasing the initial coulombic efficiency, stabilizing the cycleability as well as improving the rate capability. The sample with 2% Al doping shows the best performance, with a first cycle coulombic efficiency of 69.6% and a reversible capacity of 597.7 mA h g(−1) after 100 cycles. Even at the high current density of 1600 mA g(−1), it still retained a capacity of 558 mA h g(−1).