C–C and C–H coupling reactions by Fe(3)O(4)/KCC-1/APTPOSS supported palladium-salen-bridged ionic networks as a reusable catalyst

This study investigates the potential application of an efficient, easily recoverable and reusable magnetically separable Fe(3)O(4)/KCC-1/APTPOSS nanoparticle-supported salen/Pd(ii) catalyst for C–C and C–H cross-couplings. The Fe(3)O(4)/KCC-1/APTPOSS/salen/Pd(ii) MNPs were thoroughly characterized...

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Detalles Bibliográficos
Autores principales: Hassankhani, Asadollah, Sadeghzadeh, Seyed Mohsen, Zhiani, Rahele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078613/
https://www.ncbi.nlm.nih.gov/pubmed/35539873
http://dx.doi.org/10.1039/c8ra00485d
Descripción
Sumario:This study investigates the potential application of an efficient, easily recoverable and reusable magnetically separable Fe(3)O(4)/KCC-1/APTPOSS nanoparticle-supported salen/Pd(ii) catalyst for C–C and C–H cross-couplings. The Fe(3)O(4)/KCC-1/APTPOSS/salen/Pd(ii) MNPs were thoroughly characterized by using TEM, FE-SEM, TGA, XRD, VSM, FT-IR, ICP-MS, and BET. This observation was exploited in the direct and selective chemical reaction of 2-acetyl-benzaldehyde with cyclopentadiene for the synthesis of pentafulvene. The recycled catalyst has been analyzed by ICP-MS showing only minor changes in the morphology after the reaction, thus confirming the robustness of the catalyst.

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