Cargando…

The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries

Here, we studied the effect of thermal annealing on the microstructure and cyclic stability of a (Ti, Fe)-alloyed Si thin-film fabricated by a simple sputtering deposition method for Li-ion battery (LIB) anodes. The anode samples annealed at different temperatures (300–600 °C) were subjected to micr...

Descripción completa

Detalles Bibliográficos
Autores principales: Oh, Minsub, Kim, Ilwhan, Lee, Hoo-Jeong, Hyun, Seungmin, Kang, Chiwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078669/
https://www.ncbi.nlm.nih.gov/pubmed/35541878
http://dx.doi.org/10.1039/c7ra13172k
_version_ 1784702386006130688
author Oh, Minsub
Kim, Ilwhan
Lee, Hoo-Jeong
Hyun, Seungmin
Kang, Chiwon
author_facet Oh, Minsub
Kim, Ilwhan
Lee, Hoo-Jeong
Hyun, Seungmin
Kang, Chiwon
author_sort Oh, Minsub
collection PubMed
description Here, we studied the effect of thermal annealing on the microstructure and cyclic stability of a (Ti, Fe)-alloyed Si thin-film fabricated by a simple sputtering deposition method for Li-ion battery (LIB) anodes. The anode samples annealed at different temperatures (300–600 °C) were subjected to microstructure analysis and LIB performance test. The (Ti, Fe)-alloyed Si thin-film anode delivered a high capacity of 1563 mA h g(−1) for 100 cycles at 0.1 A g(−1) with nearly 100% capacity retention. Post-mortem analysis using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) disclosed the microstructural changes of the cycled anodes, revealing that (Ti, Fe) silicides served as a structural buffer against the large volume change of active Si during cycling for enhanced LIB performance.
format Online
Article
Text
id pubmed-9078669
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90786692022-05-09 The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries Oh, Minsub Kim, Ilwhan Lee, Hoo-Jeong Hyun, Seungmin Kang, Chiwon RSC Adv Chemistry Here, we studied the effect of thermal annealing on the microstructure and cyclic stability of a (Ti, Fe)-alloyed Si thin-film fabricated by a simple sputtering deposition method for Li-ion battery (LIB) anodes. The anode samples annealed at different temperatures (300–600 °C) were subjected to microstructure analysis and LIB performance test. The (Ti, Fe)-alloyed Si thin-film anode delivered a high capacity of 1563 mA h g(−1) for 100 cycles at 0.1 A g(−1) with nearly 100% capacity retention. Post-mortem analysis using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) disclosed the microstructural changes of the cycled anodes, revealing that (Ti, Fe) silicides served as a structural buffer against the large volume change of active Si during cycling for enhanced LIB performance. The Royal Society of Chemistry 2018-03-01 /pmc/articles/PMC9078669/ /pubmed/35541878 http://dx.doi.org/10.1039/c7ra13172k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Oh, Minsub
Kim, Ilwhan
Lee, Hoo-Jeong
Hyun, Seungmin
Kang, Chiwon
The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries
title The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries
title_full The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries
title_fullStr The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries
title_full_unstemmed The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries
title_short The role of thermal annealing on the microstructures of (Ti, Fe)-alloyed Si thin-film anodes for high-performance Li-ion batteries
title_sort role of thermal annealing on the microstructures of (ti, fe)-alloyed si thin-film anodes for high-performance li-ion batteries
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078669/
https://www.ncbi.nlm.nih.gov/pubmed/35541878
http://dx.doi.org/10.1039/c7ra13172k
work_keys_str_mv AT ohminsub theroleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT kimilwhan theroleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT leehoojeong theroleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT hyunseungmin theroleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT kangchiwon theroleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT ohminsub roleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT kimilwhan roleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT leehoojeong roleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT hyunseungmin roleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries
AT kangchiwon roleofthermalannealingonthemicrostructuresoftifealloyedsithinfilmanodesforhighperformanceliionbatteries