Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties

Novel protic ionic liquids (PILs) were synthesized by neutralization of primary alkylamines with bis(trifluoromethanesulfonyl)amide acid. An extensive hydrogen bonding network in these PILs was observed via lower thermal stability, temperature dependent inversion from non-Newtonian to Newtonian flui...

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Detalles Bibliográficos
Autores principales: Hoque, Mahfuzul, Thomas, Morgan L., Miran, Muhammed Shah, Akiyama, Mio, Marium, Mayeesha, Ueno, Kazuhide, Dokko, Kaoru, Watanabe, Masayoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078737/
https://www.ncbi.nlm.nih.gov/pubmed/35540830
http://dx.doi.org/10.1039/c8ra00402a
Descripción
Sumario:Novel protic ionic liquids (PILs) were synthesized by neutralization of primary alkylamines with bis(trifluoromethanesulfonyl)amide acid. An extensive hydrogen bonding network in these PILs was observed via lower thermal stability, temperature dependent inversion from non-Newtonian to Newtonian fluidic behavior, and lower ionicity compared to their secondary and tertiary analogues.

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