Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties

Novel protic ionic liquids (PILs) were synthesized by neutralization of primary alkylamines with bis(trifluoromethanesulfonyl)amide acid. An extensive hydrogen bonding network in these PILs was observed via lower thermal stability, temperature dependent inversion from non-Newtonian to Newtonian flui...

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Autores principales: Hoque, Mahfuzul, Thomas, Morgan L., Miran, Muhammed Shah, Akiyama, Mio, Marium, Mayeesha, Ueno, Kazuhide, Dokko, Kaoru, Watanabe, Masayoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078737/
https://www.ncbi.nlm.nih.gov/pubmed/35540830
http://dx.doi.org/10.1039/c8ra00402a
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author Hoque, Mahfuzul
Thomas, Morgan L.
Miran, Muhammed Shah
Akiyama, Mio
Marium, Mayeesha
Ueno, Kazuhide
Dokko, Kaoru
Watanabe, Masayoshi
author_facet Hoque, Mahfuzul
Thomas, Morgan L.
Miran, Muhammed Shah
Akiyama, Mio
Marium, Mayeesha
Ueno, Kazuhide
Dokko, Kaoru
Watanabe, Masayoshi
author_sort Hoque, Mahfuzul
collection PubMed
description Novel protic ionic liquids (PILs) were synthesized by neutralization of primary alkylamines with bis(trifluoromethanesulfonyl)amide acid. An extensive hydrogen bonding network in these PILs was observed via lower thermal stability, temperature dependent inversion from non-Newtonian to Newtonian fluidic behavior, and lower ionicity compared to their secondary and tertiary analogues.
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spelling pubmed-90787372022-05-09 Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties Hoque, Mahfuzul Thomas, Morgan L. Miran, Muhammed Shah Akiyama, Mio Marium, Mayeesha Ueno, Kazuhide Dokko, Kaoru Watanabe, Masayoshi RSC Adv Chemistry Novel protic ionic liquids (PILs) were synthesized by neutralization of primary alkylamines with bis(trifluoromethanesulfonyl)amide acid. An extensive hydrogen bonding network in these PILs was observed via lower thermal stability, temperature dependent inversion from non-Newtonian to Newtonian fluidic behavior, and lower ionicity compared to their secondary and tertiary analogues. The Royal Society of Chemistry 2018-03-09 /pmc/articles/PMC9078737/ /pubmed/35540830 http://dx.doi.org/10.1039/c8ra00402a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Hoque, Mahfuzul
Thomas, Morgan L.
Miran, Muhammed Shah
Akiyama, Mio
Marium, Mayeesha
Ueno, Kazuhide
Dokko, Kaoru
Watanabe, Masayoshi
Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
title Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
title_full Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
title_fullStr Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
title_full_unstemmed Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
title_short Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
title_sort protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical properties
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078737/
https://www.ncbi.nlm.nih.gov/pubmed/35540830
http://dx.doi.org/10.1039/c8ra00402a
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