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The mechanistic investigations of photochemical carbonyl elimination and oxidative addition reactions of (η(5)-C(5)H(5))M(CO)(3), (M = Mn and Re) complexes
We used computational methods to explore the mechanisms of the photochemical decarbonylation and the Si–H bond activation reaction of the group 7 organometallic compounds, η(5)-CpM(CO)(3) (M = Mn and Re). The energies of both conical intersections and the intersystem crossings, which play a decisive...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078969/ https://www.ncbi.nlm.nih.gov/pubmed/35541546 http://dx.doi.org/10.1039/c8ra01118d |