Four 3D coordination polymers based on layers with single syn–anti carboxylate bridges: synthesis, structures, and magnetic properties

Four novel coordination polymers (CPs) based on a new 4-(3,5-dicarboxylphenyl) picolinic acid ligands (H(3)L), [M(3)(L)(2)(H(2)O)(6)]·4H(2)O (M(3) = Mn(3), 1; Co(3), 2; Ni(3), 3, Co(1.01)Ni(1.99), 4), have been hydrothermally synthesized, and structurally and magnetically characterized. In these isomorphous CPs, octahedrally coordinated metal ions are linked by the single syn–anti carboxylate bridge (μ-COO) to give linear trinuclear motifs. The motifs are connected through the other single syn–anti carboxylate bridge (μ-COO) to give a 2D (4,4) layer, and the layers are interlinked by the L ligands into 3D frameworks. Magnetic measurement indicates that antiferromagnetic interactions between metal ions are mediated through the single syn–anti carboxylate bridges in 1 and 2, while the same carboxylate bridges in 3 transmit ferromagnetic couplings. The bimetallic CP 4 shows interesting complicated magnetic behaviors due to the competition effect of Co(ii) and Ni(ii) ions.