Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant

An efficient copper-catalyzed direct o-acyloxylation of 2-phenylpyridine with carboxylic acids using oxygen as the oxidant has been developed. Various acids including aromatic acids, cinnamic acids and aliphatic acids are effective acyloxylation reagents and provide the desired products in moderate...

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Detalles Bibliográficos
Autores principales: Wang, Feifan, Lin, Zhiyang, Yu, Weisheng, Hu, Qingdong, Shu, Chao, Zhang, Wu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080246/
https://www.ncbi.nlm.nih.gov/pubmed/35542218
http://dx.doi.org/10.1039/c8ra01974f
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author Wang, Feifan
Lin, Zhiyang
Yu, Weisheng
Hu, Qingdong
Shu, Chao
Zhang, Wu
author_facet Wang, Feifan
Lin, Zhiyang
Yu, Weisheng
Hu, Qingdong
Shu, Chao
Zhang, Wu
author_sort Wang, Feifan
collection PubMed
description An efficient copper-catalyzed direct o-acyloxylation of 2-phenylpyridine with carboxylic acids using oxygen as the oxidant has been developed. Various acids including aromatic acids, cinnamic acids and aliphatic acids are effective acyloxylation reagents and provide the desired products in moderate to excellent yields. The reaction proceeds well under an oxygen atmosphere, making this method potentially practical.
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spelling pubmed-90802462022-05-09 Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant Wang, Feifan Lin, Zhiyang Yu, Weisheng Hu, Qingdong Shu, Chao Zhang, Wu RSC Adv Chemistry An efficient copper-catalyzed direct o-acyloxylation of 2-phenylpyridine with carboxylic acids using oxygen as the oxidant has been developed. Various acids including aromatic acids, cinnamic acids and aliphatic acids are effective acyloxylation reagents and provide the desired products in moderate to excellent yields. The reaction proceeds well under an oxygen atmosphere, making this method potentially practical. The Royal Society of Chemistry 2018-05-03 /pmc/articles/PMC9080246/ /pubmed/35542218 http://dx.doi.org/10.1039/c8ra01974f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Feifan
Lin, Zhiyang
Yu, Weisheng
Hu, Qingdong
Shu, Chao
Zhang, Wu
Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
title Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
title_full Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
title_fullStr Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
title_full_unstemmed Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
title_short Copper-catalyzed C–H acyloxylation of 2-phenylpyridine using oxygen as the oxidant
title_sort copper-catalyzed c–h acyloxylation of 2-phenylpyridine using oxygen as the oxidant
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080246/
https://www.ncbi.nlm.nih.gov/pubmed/35542218
http://dx.doi.org/10.1039/c8ra01974f
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AT yuweisheng coppercatalyzedchacyloxylationof2phenylpyridineusingoxygenastheoxidant
AT huqingdong coppercatalyzedchacyloxylationof2phenylpyridineusingoxygenastheoxidant
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