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A weaker donor shows higher oxidation state upon aggregation
The charge-transfer between TTFs and I(2) shows that the stronger donor TTF1 is in a cation radical state and the weaker donor TTF2 is neutral in solution, whereas TTF1 exists as a cation radical and TTF2 is dicationic in complexes. The dicationic and neutral states of TTF2 are reversible upon aggre...
Autores principales: | Ma, Longfei, Peng, Haili, Lu, Xiaofeng, Liu, Lei, Shao, Xiangfeng |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080441/ https://www.ncbi.nlm.nih.gov/pubmed/35539261 http://dx.doi.org/10.1039/c8ra02956c |
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