Decontamination of radioactive cesium ions using ordered mesoporous monetite

We report herein the fabrication of an environmentally friendly, low-cost and efficient nanostructured mesoporous monetite plate-like mineral (CaHPO(4)) as an adsorbent for removal of radioactive cesium ions from aqueous solutions. The phase and textural features of the synthesized mesoporous monetite were well characterized by XRD, FTIR, SEM, HRTEM, DLS, TGA/TDA, and N(2) adsorption/desorption techniques. The results indicate that the cesium ions were effectively adsorbed by the mesoporous monetite ion-exchanger (MMT-IEX) above pH 9.0. Different kinetic and isotherm models were applied to characterize the cesium adsorption process. The fabricated monetite exhibited a monolayer adsorption capacity up to 60.33 mg g(−1) at pH of 9.5. The collected data revealed the higher ability of CaHPO(4) for the removal of Cs(i) from aqueous media in an efficient way.