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Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal
Hierarchically porous SiO(2)/C hollow microspheres (HPSCHMs) were synthesized by a hydrothermal and NaOH-etching combined route. The adsorption performance of the prepared HPSCHMs was investigated to remove Congo Red (CR) in aqueous solution. The results show that the synthesized composite possesses...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080780/ https://www.ncbi.nlm.nih.gov/pubmed/35541001 http://dx.doi.org/10.1039/c8ra02988a |
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author | Wang, Jie Xiao, Longya Wen, Shuai Chen, Nuo Dai, Zhiyin Deng, Junyang Nie, Longhui Min, Jie |
author_facet | Wang, Jie Xiao, Longya Wen, Shuai Chen, Nuo Dai, Zhiyin Deng, Junyang Nie, Longhui Min, Jie |
author_sort | Wang, Jie |
collection | PubMed |
description | Hierarchically porous SiO(2)/C hollow microspheres (HPSCHMs) were synthesized by a hydrothermal and NaOH-etching combined route. The adsorption performance of the prepared HPSCHMs was investigated to remove Congo Red (CR) in aqueous solution. The results show that the synthesized composite possesses a hollow microspherical structure with hierarchical pores and a diameter of about 100–200 nm, and its surface area is up to 1154 m(2) g(−1). This material exhibits a remarkable adsorption performance for CR in solution, and its maximum adsorption amount for CR can reach up to 2512 mg g(−1). It shows faster adsorption and much higher adsorption capacity than the commercial AC and γ-Al(2)O(3) samples under the same conditions. The studies of the kinetics and thermodynamics indicate that the adsorption of CR on the PHSCHM sample obeys the pseudo-second order model well and belongs to physisorption. The adsorption activation energy is about 7.72 kJ mol(−1). In view of the hierarchically meso–macroporous structure, large surface area and pore volume, the HPSCHM material could be a promising adsorbent for removal of pollutants, and it could also be used as a catalyst support. |
format | Online Article Text |
id | pubmed-9080780 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90807802022-05-09 Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal Wang, Jie Xiao, Longya Wen, Shuai Chen, Nuo Dai, Zhiyin Deng, Junyang Nie, Longhui Min, Jie RSC Adv Chemistry Hierarchically porous SiO(2)/C hollow microspheres (HPSCHMs) were synthesized by a hydrothermal and NaOH-etching combined route. The adsorption performance of the prepared HPSCHMs was investigated to remove Congo Red (CR) in aqueous solution. The results show that the synthesized composite possesses a hollow microspherical structure with hierarchical pores and a diameter of about 100–200 nm, and its surface area is up to 1154 m(2) g(−1). This material exhibits a remarkable adsorption performance for CR in solution, and its maximum adsorption amount for CR can reach up to 2512 mg g(−1). It shows faster adsorption and much higher adsorption capacity than the commercial AC and γ-Al(2)O(3) samples under the same conditions. The studies of the kinetics and thermodynamics indicate that the adsorption of CR on the PHSCHM sample obeys the pseudo-second order model well and belongs to physisorption. The adsorption activation energy is about 7.72 kJ mol(−1). In view of the hierarchically meso–macroporous structure, large surface area and pore volume, the HPSCHM material could be a promising adsorbent for removal of pollutants, and it could also be used as a catalyst support. The Royal Society of Chemistry 2018-05-30 /pmc/articles/PMC9080780/ /pubmed/35541001 http://dx.doi.org/10.1039/c8ra02988a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Wang, Jie Xiao, Longya Wen, Shuai Chen, Nuo Dai, Zhiyin Deng, Junyang Nie, Longhui Min, Jie Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal |
title | Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal |
title_full | Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal |
title_fullStr | Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal |
title_full_unstemmed | Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal |
title_short | Hierarchically porous SiO(2)/C hollow microspheres: a highly efficient adsorbent for Congo Red removal |
title_sort | hierarchically porous sio(2)/c hollow microspheres: a highly efficient adsorbent for congo red removal |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080780/ https://www.ncbi.nlm.nih.gov/pubmed/35541001 http://dx.doi.org/10.1039/c8ra02988a |
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