A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions

A low-cost and efficient thio- and selenocyanation strategy for electron-rich arenes has been developed under constant-current electrolytic conditions in an undivided cell. This strategy is versatile for various (hetero)aromatic compounds such as indole, pyrrole, aniline and anisole under mild condi...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Xing, Wang, Chenguang, Jiang, Hong, Sun, Linhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9081088/
https://www.ncbi.nlm.nih.gov/pubmed/35541747
http://dx.doi.org/10.1039/c8ra04407d
_version_ 1784702934623191040
author Zhang, Xing
Wang, Chenguang
Jiang, Hong
Sun, Linhao
author_facet Zhang, Xing
Wang, Chenguang
Jiang, Hong
Sun, Linhao
author_sort Zhang, Xing
collection PubMed
description A low-cost and efficient thio- and selenocyanation strategy for electron-rich arenes has been developed under constant-current electrolytic conditions in an undivided cell. This strategy is versatile for various (hetero)aromatic compounds such as indole, pyrrole, aniline and anisole under mild conditions without any catalyst or oxidant. Readily available salts NH(4)SCN and KSeCN are employed respectively as the sole reagent.
format Online
Article
Text
id pubmed-9081088
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90810882022-05-09 A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions Zhang, Xing Wang, Chenguang Jiang, Hong Sun, Linhao RSC Adv Chemistry A low-cost and efficient thio- and selenocyanation strategy for electron-rich arenes has been developed under constant-current electrolytic conditions in an undivided cell. This strategy is versatile for various (hetero)aromatic compounds such as indole, pyrrole, aniline and anisole under mild conditions without any catalyst or oxidant. Readily available salts NH(4)SCN and KSeCN are employed respectively as the sole reagent. The Royal Society of Chemistry 2018-06-14 /pmc/articles/PMC9081088/ /pubmed/35541747 http://dx.doi.org/10.1039/c8ra04407d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhang, Xing
Wang, Chenguang
Jiang, Hong
Sun, Linhao
A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
title A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
title_full A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
title_fullStr A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
title_full_unstemmed A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
title_short A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
title_sort low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9081088/
https://www.ncbi.nlm.nih.gov/pubmed/35541747
http://dx.doi.org/10.1039/c8ra04407d
work_keys_str_mv AT zhangxing alowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT wangchenguang alowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT jianghong alowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT sunlinhao alowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT zhangxing lowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT wangchenguang lowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT jianghong lowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions
AT sunlinhao lowcostelectrochemicalthioandselenocyanationstrategyforelectronricharenesundercatalystandoxidantfreeconditions

Ejemplares similares