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Synthesis of high cis-1,4 polybutadiene with narrow molecular weight distribution via a neodymium-based binary catalyst

This work explores the synthesis of polybutadiene (PB) with high cis-1,4 unit content and narrow molecular weight distribution using a neodymium-based complex, consisting of neodymium(iii) trifluoromethane sulfonate (Nd(CF(3)SO(3))(3)) and coordinated with tris(2-ethylhexyl)phosphate (TOP). The comp...

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Detalles Bibliográficos
Autores principales: Liu, Jie, Fan, Xiaodong, Min, Xin, Zhu, Xiuzhong, Zhao, Na, Wang, Zichao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9081107/
https://www.ncbi.nlm.nih.gov/pubmed/35541701
http://dx.doi.org/10.1039/c8ra02656d