Cargando…

Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation

The development of electrocatalysts for the Oxygen Evolution Reaction (OER) requires extensive and challenging research for the water splitting and fuel cell applications. Herein, we report a low-cost CoFe(2)O(4)/biomass carbon (CFO@BC/Zn) hybrid from Co-enriched Sulfate Reducing Bacteria (Co-SRB) a...

Descripción completa

Detalles Bibliográficos
Autores principales: Bi, Songhu, Li, Jingde, Zhong, Qin, Chen, Chuntan, Zhang, Qiyi, Yao, Yongyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9081556/
https://www.ncbi.nlm.nih.gov/pubmed/35539754
http://dx.doi.org/10.1039/c8ra02959h
_version_ 1784703011298213888
author Bi, Songhu
Li, Jingde
Zhong, Qin
Chen, Chuntan
Zhang, Qiyi
Yao, Yongyi
author_facet Bi, Songhu
Li, Jingde
Zhong, Qin
Chen, Chuntan
Zhang, Qiyi
Yao, Yongyi
author_sort Bi, Songhu
collection PubMed
description The development of electrocatalysts for the Oxygen Evolution Reaction (OER) requires extensive and challenging research for the water splitting and fuel cell applications. Herein, we report a low-cost CoFe(2)O(4)/biomass carbon (CFO@BC/Zn) hybrid from Co-enriched Sulfate Reducing Bacteria (Co-SRB) as an electrocatalyst for OER. The electrocatalyst exhibits a low potential of 1.53 V at a current density 10 mA cm(−2) and Tafel slope of 86 mV dec(−1). This method does not require high-cost or long periods of preparation. The density-functional theory (DFT) calculations show a small barrier for oxygen conversion on Fe(3+) of CFO (100) surface. The synthesis of CFO@BC/Zn may be a new approach for obtaining low-priced electrocatalysts for OER.
format Online
Article
Text
id pubmed-9081556
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90815562022-05-09 Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation Bi, Songhu Li, Jingde Zhong, Qin Chen, Chuntan Zhang, Qiyi Yao, Yongyi RSC Adv Chemistry The development of electrocatalysts for the Oxygen Evolution Reaction (OER) requires extensive and challenging research for the water splitting and fuel cell applications. Herein, we report a low-cost CoFe(2)O(4)/biomass carbon (CFO@BC/Zn) hybrid from Co-enriched Sulfate Reducing Bacteria (Co-SRB) as an electrocatalyst for OER. The electrocatalyst exhibits a low potential of 1.53 V at a current density 10 mA cm(−2) and Tafel slope of 86 mV dec(−1). This method does not require high-cost or long periods of preparation. The density-functional theory (DFT) calculations show a small barrier for oxygen conversion on Fe(3+) of CFO (100) surface. The synthesis of CFO@BC/Zn may be a new approach for obtaining low-priced electrocatalysts for OER. The Royal Society of Chemistry 2018-06-21 /pmc/articles/PMC9081556/ /pubmed/35539754 http://dx.doi.org/10.1039/c8ra02959h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Bi, Songhu
Li, Jingde
Zhong, Qin
Chen, Chuntan
Zhang, Qiyi
Yao, Yongyi
Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
title Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
title_full Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
title_fullStr Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
title_full_unstemmed Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
title_short Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
title_sort low-cost cofe(2)o(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9081556/
https://www.ncbi.nlm.nih.gov/pubmed/35539754
http://dx.doi.org/10.1039/c8ra02959h
work_keys_str_mv AT bisonghu lowcostcofe2o4biomasscarbonhybridfrommetalenrichedsulfatereducingbacteriaasanelectrocatalystforwateroxidation
AT lijingde lowcostcofe2o4biomasscarbonhybridfrommetalenrichedsulfatereducingbacteriaasanelectrocatalystforwateroxidation
AT zhongqin lowcostcofe2o4biomasscarbonhybridfrommetalenrichedsulfatereducingbacteriaasanelectrocatalystforwateroxidation
AT chenchuntan lowcostcofe2o4biomasscarbonhybridfrommetalenrichedsulfatereducingbacteriaasanelectrocatalystforwateroxidation
AT zhangqiyi lowcostcofe2o4biomasscarbonhybridfrommetalenrichedsulfatereducingbacteriaasanelectrocatalystforwateroxidation
AT yaoyongyi lowcostcofe2o4biomasscarbonhybridfrommetalenrichedsulfatereducingbacteriaasanelectrocatalystforwateroxidation