Highly efficient and recyclable water-soluble fullerene-supported PdCl(2) nanocatalyst in Suzuki–Miyaura cross-coupling reaction

A water-soluble fullerene-supported PdCl(2) nanocatalyst [C(60)-TEG(S)/PdCl(2)] was prepared by coordination of water-soluble fullerene nanoparticles with palladium chloride. In pure water, the catalytic activity of nanocatalyst [C(60)-TEG(S)/PdCl(2)] for Suzuki–Miyaura cross-coupling reaction was i...

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Detalles Bibliográficos
Autores principales: Li, Jingbo, Huo, Ping, Zheng, Junwei, Zhou, Xiuming, Liu, Wanyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082040/
https://www.ncbi.nlm.nih.gov/pubmed/35539195
http://dx.doi.org/10.1039/c8ra03754j
Descripción
Sumario:A water-soluble fullerene-supported PdCl(2) nanocatalyst [C(60)-TEG(S)/PdCl(2)] was prepared by coordination of water-soluble fullerene nanoparticles with palladium chloride. In pure water, the catalytic activity of nanocatalyst [C(60)-TEG(S)/PdCl(2)] for Suzuki–Miyaura cross-coupling reaction was investigated under different reaction conditions. The results showed that biphenyl compounds could be synthesized in high yields at room temperature using 0.01 mol% of [C(60)-TEG(S)/PdCl(2)] as the catalyst and K(2)CO(3) as the base with the reaction time of 4 h. The catalyst was recycled five times, and the yield clearly did not decrease.

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