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In situ synthesis of metal embedded nitrogen doped carbon nanotubes as an electrocatalyst for the oxygen reduction reaction with high activity and stability

In this work, a Co–N doped carbon nanotube (CNT) catalyst was fabricated via a simple pyrolysis approach and the effects of solvothermal processing on the catalytic activity of the as-prepared material were investigated in detail. The results show that after solvothermal processing (Co-NC) the catal...

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Detalles Bibliográficos
Autores principales: Yin, Yanhong, Zhang, Hengbo, Gao, Rongzhen, Wang, Aili, Mao, Xinxin, Dong, Hongyu, Yang, Shuting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082301/
https://www.ncbi.nlm.nih.gov/pubmed/35542145
http://dx.doi.org/10.1039/c8ra03139h
Descripción
Sumario:In this work, a Co–N doped carbon nanotube (CNT) catalyst was fabricated via a simple pyrolysis approach and the effects of solvothermal processing on the catalytic activity of the as-prepared material were investigated in detail. The results show that after solvothermal processing (Co-NC) the catalyst has a more homogeneous anemone structure, a higher nitrogen content, a larger BET surface area and a higher degree of graphitization compared to the catalyst produced after non-solvothermal processing (Co-MA). The results of electrochemical tests indicate that Co-NC, compared to commercial 20% Pt/C and Co-MA, has an improved mass transfer process and sufficient active site exposure, which brings about superb oxygen reduction electrocatalytic activity, a higher reduction potential (−0.2 V vs. Ag/AgCl), a limiting diffusion current (5.44 mA cm(−2)) and excellent stability in 0.1 M KOH solution.