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Reaction of FcC[triple bond, length as m-dash]CC(O)R (Fc = ferrocenyl) with Ru(3)(CO)(12) leading to unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted triruthenium clusters
The reaction of Ru(3)(CO)(12) with ferrocene-containing alkynyl ketones FcC[triple bond, length as m-dash]CC(O)R (Fc = ferrocenyl; R = Ph (1); 2-thienyl (2); 4-CH(3)O–Ph (3); 4-NH(2)–Ph (4); 4-NO(2)–Ph (5); ferrocenyl (6)) proceeds in toluene with the formation of triruthenium clusters (1a–6a), ruth...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082558/ https://www.ncbi.nlm.nih.gov/pubmed/35539793 http://dx.doi.org/10.1039/c8ra04548h |