1,2,3-Triazole based bisphosphine, 5-(diphenylphosphanyl)-1-(2-(diphenylphosphanyl)-phenyl)-4-phenyl-1H-1,2,3-triazole: an ambidentate ligand with switchable coordination modes

The reaction of 1-(2-bromophenyl)-4-phenyl-1H-1,2,3-triazole (1) with Ph(2)PCl yielded bisphosphine, 5-(diphenylphosphanyl)-1-(2-(diphenylphosphanyl)phenyl)-4-phenyl-1H-1,2,3-triazole (2). Bisphosphine 2 exhibits ambidentate character in either the κ(2)-P,N or κ(2)-P,P coordination mode. Treatment o...

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Detalles Bibliográficos
Autores principales: Radhakrishna, Latchupatula, Pandey, Madhusudan K., Balakrishna, Maravanji S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082604/
https://www.ncbi.nlm.nih.gov/pubmed/35539783
http://dx.doi.org/10.1039/c8ra04086a

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