Novel Mn(4+)-activated LiLaMgWO(6) far-red emitting phosphors: high photoluminescence efficiency, good thermal stability, and potential applications in plant cultivation LEDs

Double perovskite-based LiLaMgWO(6):Mn(4+) (LLMW:Mn(4+)) red phosphors were synthesized by traditional solid-state route under high temperature, and they showed bright far-red emission under excitation of 344 nm. The crystal structure, luminescence performance, internal quantum efficiency, fluorescence decay lifetimes, and thermal stability were investigated in detail. All samples exhibited far-red emissions around 713 nm due to the (2)E(g) → (4)A(2g) transition of Mn(4+) under excitation of near-ultraviolet and blue light, and the optimal doping concentration of Mn(4+) was about 0.7 mol%. The CIE chromaticity coordinates of the LLMW:0.7% Mn(4+) sample were (0.7253, 0.2746), and they were located at the border of the chromaticity diagram, indicating that the phosphors had high color purity. Furthermore, the internal quantum efficiency of LLMW:0.7% Mn(4+) phosphors reached up to 69.1%, which was relatively higher than those of the reported Mn(4+)-doped red phosphors. Moreover, the sample displayed good thermal stability; the emission intensity of LLMW:0.7% Mn(4+) phosphors at 423 K was 49% of the initial value at 303 K, while the activation energy was 0.39 eV. Importantly, there was a broad spectral overlap between the emission band of LLMW:Mn(4+) phosphors and the absorption band of phytochrome P(FR) under near-ultraviolet light. All of these properties and phenomena illustrate that the LLMW:Mn(4+) phosphors are potential far-red phosphors for applications in plant cultivation LEDs.