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Preparation, characterization and catalytic application of nano-Fe(3)O(4)@SiO(2)@(CH(2))(3)OCO(2)Na as a novel basic magnetic nanocatalyst for the synthesis of new pyranocoumarin derivatives
We present a study on the synthesis, characterization and application of sodium carbonate tag silica-coated nano-Fe(3)O(4) (Fe(3)O(4)@SiO(2)@(CH(2))(3)OCO(2)Na) as a novel and efficient heterogeneous basic catalyst. The described catalyst was fully characterized via FT-IR, X-ray diffraction (XRD), e...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9083525/ https://www.ncbi.nlm.nih.gov/pubmed/35542713 http://dx.doi.org/10.1039/c8ra05501g |
Sumario: | We present a study on the synthesis, characterization and application of sodium carbonate tag silica-coated nano-Fe(3)O(4) (Fe(3)O(4)@SiO(2)@(CH(2))(3)OCO(2)Na) as a novel and efficient heterogeneous basic catalyst. The described catalyst was fully characterized via FT-IR, X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), and field emission scanning electron microscopy (FE-SEM). The reported novel magnetic nanocatalyst presents an excellent activity and catalytic performance for the synthesis of a novel series of pyranocoumarins through the reaction of dialkyl acetylenedicarboxylates and 5,7-dihydroxy coumarin derivatives at 100 °C under solvent-free conditions. |
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