Temporal–spatial-resolved mapping of the electrical double layer changes by surface plasmon resonance imaging

An electrical double layer (EDL) is a specific distribution of ions at the electrolyte/electrode interface. As EDL plays a decisive role in the interfacial physical and chemical characteristics, a comprehensive and quantitative understanding of the EDL structure and its change dynamics is important for a wide range of fields, ranging from electrochemistry, energy storage and semiconductor materials to biotechnology. In this paper, we proposed a proof of concept method for temporal- and spatial-resolved mapping of the EDL structure and its change dynamics. A potential was applied on the interface and the potential induced ion re-arrangement process was monitored by surface plasmon resonance (SPR) imaging in real time. NaCl experiments were repeated six times and the coefficient of variation of the results was 5.17%, confirming the potential-induced SPR response. Experiments with different potential excitations, ion concentrations and species were performed and results indicated that the electron density change and ion re-arrangement contributed comparably to the potential induced SPR response. Additionally, the lateral distribution of the EDL formed at the interface between NaCl solutions and an Au film coated with arrays of 11-MUA spots was mapped. This method is temporally and spatially resolved, and thus has the potential to be a promising tool for EDL studies at heterogeneous interfaces.