Cargando…
A H(2)O(2)/HBr system – several directions but one choice: oxidation–bromination of secondary alcohols into mono- or dibromo ketones
In this work we found that a H(2)O(2)–HBr(aq) system allows synthesis of α-monobromo ketones and α,α′-dibromo ketones from aliphatic and secondary benzylic alcohols with yields up to 91%. It is possible to selectively direct the process toward the formation of mono- or dibromo ketones by varying the...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9084404/ https://www.ncbi.nlm.nih.gov/pubmed/35548402 http://dx.doi.org/10.1039/c8ra04885a |