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Computational study on palladium-catalyzed alkenylation of remote δ-C(sp(3))–H bonds with alkynes: a new understanding of mechanistic insight and origins of site-selectivity

Palladium-catalyzed alkenylation of δ-C(sp(3))–H bonds with alkynes was conducted by density functional theory calculations. The present study shows that the dimeric Pd(2)(OAc)(4) mechanism reproduces experimental observations well, including regioselectivity and provides a deep mechanistic insight...

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Detalles Bibliográficos
Autores principales:	Yan, Hui-Min, Tian, Ye, Li, Niu, Chang, Rong, Zhang, Zhu-Xia, Zhang, Xiao-Yun, Yang, Wen-Jing, Guo, Zhen, Li, Yan-Rong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9085394/ https://www.ncbi.nlm.nih.gov/pubmed/35546853 http://dx.doi.org/10.1039/c8ra06077k

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