Advanced binder-free electrodes based on CoMn(2)O(4)@Co(3)O(4) core/shell nanostructures for high-performance supercapacitors

Three-dimensional (3D) hierarchical CoMn(2)O(4)@Co(3)O(4) core/shell nanoneedle/nanosheet arrays for high-performance supercapacitors were designed and synthesized on Ni foam by a two-step hydrothermal route. The hybrid nanostructure exhibits much more excellent capacitive behavior compared with either the pristine CoMn(2)O(4) nanoneedle arrays alone or Co(3)O(4) nanosheets alone. The formation of an interconnected pore hybrid system is quite beneficial for the facile electrolyte penetration and fast electron transport. The CoMn(2)O(4)@Co(3)O(4) electrode can achieve a high specific capacitance of 1627 F g(−1) at 1 A g(−1) and 1376 F g(−1) at 10 A g(−1). In addition, an asymmetric supercapacitor (ASC) was assembled by using the CoMn(2)O(4)@Co(3)O(4) core/shell hybrid nanostructure arrays on Ni foam as a positive electrode and activated carbon as a negative electrode in an aqueous 3 M KOH electrolyte. A specific capacitance of 125.8 F g(−1) at 1 A g(−1) (89.2% retention after 5000 charge/discharge cycles at a current density of 2 A g(−1)) and a high energy density of 44.8 W h kg(−1) was obtained. The results indicate that the obtained unique integrated CoMn(2)O(4)@Co(3)O(4) nanoarchitecture may show great promise as ASC electrodes for potential applications in energy storage.