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NiO/Ni(x)Co(3−x)O(4) porous ultrathin nanosheet/nanowire composite structures as high-performance supercapacitor electrodes

The demand for a new generation of high-safety, long-lifespan, and high-capacity power sources increases rapidly with the growth of energy consumption in the world. Here we report a facile method for preparing architecture materials made of NiO/Ni(x)Co(3−x)O(4) porous nanosheets coupled with NiO/Ni(...

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Detalles Bibliográficos
Autores principales: Jiang, Dongkai, Zheng, Maojun, You, Yuxiu, Ma, Liguo, Liu, Pengjie, Li, Fanggang, Yuan, Hao, Zhai, Zhihao, Ma, Li, Shen, Wenzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9085799/
https://www.ncbi.nlm.nih.gov/pubmed/35547508
http://dx.doi.org/10.1039/c8ra04827d
Descripción
Sumario:The demand for a new generation of high-safety, long-lifespan, and high-capacity power sources increases rapidly with the growth of energy consumption in the world. Here we report a facile method for preparing architecture materials made of NiO/Ni(x)Co(3−x)O(4) porous nanosheets coupled with NiO/Ni(x)Co(3−x)O(4) porous nanowires grown in situ on nickel foams using a hydrothermal method without any binder followed by a heat treatment process. The nanosheet-shaped NiO/Ni(x)Co(3−x)O(4) species in the nanosheet matrix function well as a scaffold and support for the dispersion of the Ni(x)Co(3−x)O(4) nanowires, resulting in a relatively loose and open structure within the electrode matrix. Among all composite electrodes prepared, the one annealed in air at 300 °C displays the best electrochemical behavior, achieving a specific capacitance of 270 mF cm(−2) at 5 mA cm(−2) while maintaining excellent stability (retaining ≈ 89% of the max capacitance after 20 000 cycles), demonstrating its potential for practical application in power storage devices.