Pyrene-based metal–organic framework NU-1000 photocatalysed atom-transfer radical addition for iodoperfluoroalkylation and (Z)-selective perfluoroalkylation of olefins by visible-light irradiation

The photocatalytic atom-transfer radical addition (ATRA) of perfluoroalkyl iodides onto olefins is of potential biointerest; the relatively negative reductive potential of perfluoroalkyl iodide makes it difficult to generate the perfluoroalkyl radical by the photoinduced single-electron transfer fro...

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Detalles Bibliográficos
Autores principales: Zhang, Tiexin, Wang, Pengfang, Gao, Zirui, An, Yang, He, Cheng, Duan, Chunying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086246/
https://www.ncbi.nlm.nih.gov/pubmed/35547715
http://dx.doi.org/10.1039/c8ra06181e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086246/
https://www.ncbi.nlm.nih.gov/pubmed/35547715
http://dx.doi.org/10.1039/c8ra06181e

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