Experimental and computational preference for phosphine regioselectivity and stereoselective tripodal rotation in HOs(3)(CO)(8)(PPh(3))(2)(μ-1,2-N,C-η(1),κ(1)-C(7)H(4)NS)

The site preference for ligand substitution in the benzothiazolate-bridged cluster HOs(3)(CO)(10)(μ-1,2-N,C-η(1),κ(1)-C(7)H(4)NS) (1) has been investigated using PPh(3). 1 reacts with PPh(3) in the presence of Me(3)NO to afford the mono- and bisphosphine substituted clusters HOs(3)(CO)(9)(PPh(3))(μ-...

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Detalles Bibliográficos
Autores principales: Begum, Shahin A., Chowdhury, Md. Arshad H., Ghosh, Shishir, Tocher, Derek A., Richmond, Michael G., Yang, Li, Hardcastle, K. I., Rosenberg, Edward, Kabir, Shariff E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086258/
https://www.ncbi.nlm.nih.gov/pubmed/35547690
http://dx.doi.org/10.1039/c8ra07400c

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