Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural

Phosphorus pentoxide (P(2)O(5))/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither P(2)O(5) nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85...

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Detalles Bibliográficos
Autores principales: Jia, Songyan, He, Xinjun, Ma, Jiao, Xu, Zhanwei, Wang, Kangjun, Zhang, Z. Conrad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086339/
https://www.ncbi.nlm.nih.gov/pubmed/35547699
http://dx.doi.org/10.1039/c8ra07027j
Descripción
Sumario:Phosphorus pentoxide (P(2)O(5))/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither P(2)O(5) nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85% selectivity could be achieved within 30 min at 80 °C.

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