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Alkylhalovinylboranes: a new class of Diels–Alder dienophiles

The Diels–Alder reactions of alkylhalovinylboranes have been investigated theoretically and experimentally. Alkylhalovinylboranes presented higher reactivity than the corresponding dialkylvinylboranes. Although endo/exo selectivities were high for the reactions with cyclopentadiene, facial selectivi...

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Detalles Bibliográficos
Autores principales: Pisano, Pablo L., Pellegrinet, Silvina C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086730/
https://www.ncbi.nlm.nih.gov/pubmed/35548792
http://dx.doi.org/10.1039/c8ra07089j