Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions

Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to cyclohexane at room temperature (298 K), 1 atm H(2) pressure, and under solvent-free conditio...

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Detalles Bibliográficos
Autores principales: Benaissa, Mhamed, Alhanash, Abdullah M., Mubarak, Ahmed T., Eissa, Morad, Sahlabji, Taher, Hamdy, Mohamed S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086927/
https://www.ncbi.nlm.nih.gov/pubmed/35548652
http://dx.doi.org/10.1039/c8ra07639a
Descripción
Sumario:Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to cyclohexane at room temperature (298 K), 1 atm H(2) pressure, and under solvent-free conditions. Rhodium nanoparticles exhibited high stability, reusability and negligible leaching.

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