Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions

Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to cyclohexane at room temperature (298 K), 1 atm H(2) pressure, and under solvent-free conditio...

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Detalles Bibliográficos
Autores principales: Benaissa, Mhamed, Alhanash, Abdullah M., Mubarak, Ahmed T., Eissa, Morad, Sahlabji, Taher, Hamdy, Mohamed S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086927/
https://www.ncbi.nlm.nih.gov/pubmed/35548652
http://dx.doi.org/10.1039/c8ra07639a
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author Benaissa, Mhamed
Alhanash, Abdullah M.
Mubarak, Ahmed T.
Eissa, Morad
Sahlabji, Taher
Hamdy, Mohamed S.
author_facet Benaissa, Mhamed
Alhanash, Abdullah M.
Mubarak, Ahmed T.
Eissa, Morad
Sahlabji, Taher
Hamdy, Mohamed S.
author_sort Benaissa, Mhamed
collection PubMed
description Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to cyclohexane at room temperature (298 K), 1 atm H(2) pressure, and under solvent-free conditions. Rhodium nanoparticles exhibited high stability, reusability and negligible leaching.
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spelling pubmed-90869272022-05-10 Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions Benaissa, Mhamed Alhanash, Abdullah M. Mubarak, Ahmed T. Eissa, Morad Sahlabji, Taher Hamdy, Mohamed S. RSC Adv Chemistry Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to cyclohexane at room temperature (298 K), 1 atm H(2) pressure, and under solvent-free conditions. Rhodium nanoparticles exhibited high stability, reusability and negligible leaching. The Royal Society of Chemistry 2018-10-08 /pmc/articles/PMC9086927/ /pubmed/35548652 http://dx.doi.org/10.1039/c8ra07639a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Benaissa, Mhamed
Alhanash, Abdullah M.
Mubarak, Ahmed T.
Eissa, Morad
Sahlabji, Taher
Hamdy, Mohamed S.
Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions
title Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions
title_full Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions
title_fullStr Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions
title_full_unstemmed Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions
title_short Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions
title_sort solvent-free hydrogenation of cyclohexene over rh-tud-1 at ambient conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086927/
https://www.ncbi.nlm.nih.gov/pubmed/35548652
http://dx.doi.org/10.1039/c8ra07639a
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