NHC-Stabilized Au(10) Nanoclusters and Their Conversion to Au(25) Nanoclusters

[Image: see text] Herein, we describe the synthesis of a toroidal Au(10) cluster stabilized by N-heterocyclic carbene and halide ligands via reduction of the corresponding NHC–Au–X complexes (X = Cl, Br, I). The significant effect of the halide ligands on the formation, stability, and further conver...

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Detalles Bibliográficos
Autores principales: Lummis, Paul A., Osten, Kimberly M., Levchenko, Tetyana I., Sabooni Asre Hazer, Maryam, Malola, Sami, Owens-Baird, Bryan, Veinot, Alex J., Albright, Emily L., Schatte, Gabriele, Takano, Shinjiro, Kovnir, Kirill, Stamplecoskie, Kevin G., Tsukuda, Tatsuya, Häkkinen, Hannu, Nambo, Masakazu, Crudden, Cathleen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088291/
https://www.ncbi.nlm.nih.gov/pubmed/35557749
http://dx.doi.org/10.1021/jacsau.2c00004

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