Methane adsorption and methanol desorption of copper modified boron silicate

Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methano...

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Detalles Bibliográficos
Autores principales: Wang, Xueting, Shishkin, Alexander, Hemmingsson, Felix, Skoglundh, Magnus, Martinez-Casado, Francisco Javier, Bock, Lorenz, Idström, Alexander, Nordstierna, Lars, Härelind, Hanna, Carlsson, Per-Anders
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088827/
https://www.ncbi.nlm.nih.gov/pubmed/35558450
http://dx.doi.org/10.1039/c8ra08038k
Descripción
Sumario:Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation.

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